Ancient Godly Monarch - Chapter 3: Awakening of Genius

She became the young mistress of the most powerful family in City T by marrying the young master in place of her sister.

He was cold to her on their first nuptial night. "Just because you played some tricks to get yourself married here, you still mean nothing to me!"

However, she was calm and heartless. "Young Master Mu, don't think too highly of yourself. I despise all that is you — your money and your very being!"

After the wedding, Young Master Mu lived lavishly by spending money like flowing during the day while working his nights away busily. "You said you despised me earlier. Well, which part of me do you despise exactly, hmm?"

Luo Chenxi could not bear the harassment any longer so she tossed out the divorce papers in rage. "I can't live like this much longer..."

A good-for-nothing man married a beautiful girl but was kicked off the bed on the wedding night. Furiously, he wrote a bill of divorce and ran away.
He was schemed a car accident in which he nearly lost his life. However, it turned out to be a blessing. He swallowed the soul that passed through the outer world, thus obtained superb medical skills and martial arts.
Later on, with the silver needles and invincible martial arts, he embarked on the road of counterattacks and was committed to his great dreams.

- Description from Novelupdates

He became a teacher at the best magic academy in the empire.
….For being mistaken for someone else.