MTL - Start a Core Pod - Chapter 573 Acote

A useless prince, yet brimming with kindness and compassion—his smile as warm as sunlight, illuminating this darkened era.But that was merely a mask, hiding the poisonous and mad nature beneath.A monster lurking behind a gentle shell.A system that feeds on stolen Heroines.He will outplay destiny—and rise as the world’s ultimate villain.

One morning, after being bound to the system, MC started his routine of always being captured/ attacked by the ML.

He is a young man without a spirit root. It is believed that this denies him the chance at cultivation. However, a mysterious lady imparts a Supreme Demon Classic to him and from then on, he starts his path of cultivation.
He undergoes a total transformation to emerge as the most fearsome and powerful fiendish demon in his era, that even immortals and fiends are fearful of him, and saints are at his beck and call.
Mastering the Supreme Demon Classic is the turning point in his life. He is able to unleash his immense and divine power from within, illuminating the entire universe!

- Description from Novelupdates

At 18, Alex Kain is whisked away to Eryndor, a game-like realm where he gains 'Skill Synthesis', a talent to fuse skills into godlike powers. Battling monsters and conquering dungeons, he builds a harem of strong women drawn to his might and charm. With the power to return to Earth bearing incredible resources, Alex faces a growing threat that endangers both worlds in this epic of adventure, romance, and ambition.