One Piece: Don't Worry, I'm a Doctor - Chapter 4 - : The Flustered Little Deer

The scum’s or villain’s long road of transformation was tentatively set to the world:
The abandonment of the educated youth’s wife (Completed)
The hidden marriage of the scum film emperor (Completed)
The best brother in the world (Completed)
The Phoenix male who destroy the bridge after crossing the river (Completed)
The treasonous general (Completed)
I’m an honest man (Completed)
To become the top scorer in the School of Agriculture (Completed)
The soft rice man’s self-cultivation (Completed)
The whole world is reborn (Completed)
I want to survive on a desert island (Completed)
The stallion male who has seized the opportunity (Completed)
The perverted self-salvation (Completed)
The spring of the loafer (Completed)
The misplaced life (Completed)
The miser career (Completed)
The ghost is out of feeling (Completed)
The Queen’s favorite husband (Completed)
The vicious girl with her godfather (Completed)
I want to be a good person (Completed)
I does not tear up the family (Completed)
The perverted common plant (Completed)
The Mary Sue’s men (Completed)
Every time I was reborn, someone wants to kill me (Completed)
The old people’s counterattack path (Completed)
The global evolution (Completed)
When I became a net red (Completed)
For you, good person (Completed)
His heart had white moonlight (Completed)

- Description from Novelupdates

The world of pokemon is synonymous with young boys and girls going on a journey and facing many challenges.

This story is not like that. This story is about a SI coming into one of the most prominent companions of the pokemon world. Unlike other stories, Brock is already established and has gone on his journey. He's faced challenges and returned home to be other people's challenges. Which, there's a lot more to than most people realise.

Explore an alternate pokemon universe with an expanded cast and more mature ideals through the eyes of Brock, Gym Leader to Pewter City Gym, and family man.

Corporate slave Alexander dies with only one regret—not finishing the fantasy novel in his hands. Fate has a twisted sense of humor when he awakens as Alexander Flamingo, the perverted villain destined to be expelled and killed in that very story!Armed with complete knowledge of the original plot and a mischievous “Harem King System,” Alexander plans to rewrite his fate. No longer the one-dimensional pervert of the novel, he'll use his future knowledge to manipulate heroes, seduce heroines, and rise from disposable villain to the true mastermind of this world.The system grants him power through every relationship he builds—but can this calculating reincarnator use his second chance to avoid his predetermined death and become the ultimate Harem King? One thing's certain: this story won't follow the original script.

On her wedding day, she was humiliated; her status as the legitimate wife was instantly changed into that of a concubine.